Showing posts with label chemistry. Show all posts
Showing posts with label chemistry. Show all posts

Tuesday, 17 December 2013

The Real Costs of Parathion


     The conflict of human convenience and the wellbeing of ecosystems is a repeating issue. Parathion (usually  referring to ethyl parathion, sometimes methyl parathion), is an effective insecticide and one of the most toxic organphosphates, proved to be sometimes fatal to humans and other animals. The original intent for producing and using parathion as an insecticide are not malicious, however with more recent information the risks have become more apparent. The convenience of using parathion is not worth the consequences to natural ecosystems and human health.
An Effective Method
     Parathion is an effective and relatively cheap insecticide. It kills unwanted insect 'pests' by disrupting their nerve impulses. Pest control has played a large role in farming and the mass production of food to feed millions of people, and is also part of the monetary success for individual farmers and overall economies. Pesticides are especially needed for monocultures of food that resulted from the Green Revolution of mass factory farming, as an entire culture would be susceptible to unwanted insects. The method of factory farming has helped humans avoid Thomas Malthus' prediction that starvation would overtake the world by the year 2000, however, the use of pesticides is among the many rising issues associated with factory farming, and there are safer options than parathion such as introducing a natural predator or genetically modifying crops so that they are less susceptible to the pest. Many organic farmers have successfully raised crops without the use of any pesticides, as all pesticides do have the potential for adverse side effects. One of the reasons parathion is used is because its high toxicity makes it highly effective, but it also highly effective on other non-targeted species.

A Toxic Threat
     Other living things are not immune to the devastating effects parathion has on an organism, Parathion has proven to be especially toxic to birds such as grouse, pigeons, red-winged blackbirds, and sparrows. Amounts of dermal exposure may be fatal for birds such as house sparrows, which have 50% mortality rate after 24 hours of dermal exposure of 1.8 mg / kg on their feet. Not only do they receive exposure through the air when it is sprayed, but also because of what they prey on. Ethyl parathion has been pinned as the direct cause of death for birds in numerous instances, for example the death of fourteen Mississippi kites from insects that were contaminated by parathion in a nearby cotton field in 1994. Another occurrence was in 1982, New York, when almost 3200 birds of various species were found dead in a field containing scattered rye seeds contaminated with ethyl parathion. As birds consume contaminated seeds and insects, bioaccumulation and biomagnification occur and the buildup of parathion in their systems often kills them, and can also impair some birds exposed to nonlethal doses in terms of ability to avert predators, and reproductive behavior (such as with the mallard and bobwhite) though it is unknown whether or not parathion affects reproductive ability.
     Parathion also has the potential to damage ecosystems by damaging other wildlife. Damage to aquatic invertebrates with ethyl parathion occurs with an EC50 at less than 1.0mg/L. On an acute basis it is also toxic to fish, with the potential to throw off the delicate balance of many aquatic ecosystems with water contamination. This would have a negative impact on entire ecosystems and communities whose economies and jobs depend on the fishing industry. Honeybees also play important roles in their ecosystems as pollinators, and they too are highly susceptible to the toxicity of parathion. Pollinators are necessary for growing plants in both natural ecosystems and in growing crops for humans in farms.
     Humans are also vulnerable to the health hazards of parathion, especially those who work with the chemical or live near landfills where it is disposed of. Parathion is a carcinogen and endocrine disruptor, and has been reported to have cause an influenza-like state and has also been associated with indirect brain impairments, such as disorientation, memory loss, decreased ability to concentrate, confusion, and delayed reflexes. It has also been linked with emotional disorders such as severe depression and insomnia. Nerve damage occurs because parathion is a cholinesterase-inhibiting chemical, which prevents the breakdown of acetylcholine when it is no longer needed to trigger physical reponses to nerve impulses. The buildup of acetylcholine causes the impulses to be repeated uncontrollably, with potential direct symptoms such as muscle spasms, trembling, paralyzed breathing, irregular heartbeat, convulsions, involuntary bowel movement, and in the most extreme cases, coma or even death.

     Considering evidence proving a direct link between various adverse effects parathion has on the health of other animals such as birds, aquatic invertebrates, fish, pollinating insects, and humans, the risks are obvious and severe. The potentially risks outweigh the benefits of convenience as the real cost goes beyond monetary values, but takes a toll on health of natural ecosystems, humans and other animals.

Sources
Bird Conservancy. (n.d.). Pesticide Profile - Ethyl parathion. abc birds. Retrieved December 12, 2013, from http://www.abcbirds.org/abcprograms/policy/toxins/profiles/ethyl_parathion.html

EXTOXNET. (n.d.). Cholinesterase Inhibition. EXTOXNET. Retrieved December 12, 2013, from http://extoxnet.orst.edu/tibs/cholines.htm

The Encyclopedia of Earth. (2008, August 1). Health effects of methyl parathion Edit Classification Publishing Workflow . The Encyclopedia of Earth. Retrieved December 12, 2013, from http://www.eoearth.org/view/article/153408/

Pesticide Information Center. (n.d.). Parathion. EXTOXNET. Retrieved December 12, 2013, from http://extoxnet.orst.edu/pips/parathio.htm Reuber, M., & Cooper, S. (n.d.). PARATHION (Ethyl parathion). Beyond Pesticides. Retrieved December 12, 2013, from http://www.beyondpesticides.org/pesticides/factsheets/parathion.pdf

Wednesday, 17 April 2013

New Ideas for Renewables: Storing Energy


    There is good news and some more good news this past week for advances in renewable energy. First, a team of researchers from North America reported that they have found a way to store unused, surplus energy from renewable resources like wind turbines and solar panels. A report by Chemists from Calgary University says that they have found a way to convert electrical energy into chemical energy by means of a new catalyst. This is important because although electrical energy “cannot simply be stored”, chemical energy can, which means that this new catalyst could fill the great need for an efficient method of storing excess clean energy for when it is needed when sources have lower intake, such as slower winds or less sunlight for wind or solar power.
    Second, two members of the team, Curtis Berlinguette and Simon Trudel, have thought up another way to utilize reconverted water in fuel cells with a process that would involve no pollutants, and possibly no water loss. If the hydrogen and oxygen results from split water molecules are stored separately then reconverted into water whenever it is needed, it could result in large amounts of energy to be converted to electricity. The difficulty so far is that the conventional catalysis in the process depends on crystalline minerals that are toxic, expensive, and rare. Still, this obstacle may be overcome, as the team also said they have had a successful reaction with a new equally-useful, safer, and cheaper electro-catalyst.
    After learning more details on different renewable resources, it is especially encouraging to hear about progress and interesting to take a deeper look into the possibilities of cleaner energy. To start, being able to store energy from renewable resources would be an amazing achievement, especially considering how much it is needed. The article went into the more technical side of energy, and it helps to realize and appreciate the complexity of it all. One of the drawbacks of renewable energy sources like wind and solar power is that is amount of energy produced isn’t always constant. Depending on weather conditions (specifically wind speed and amount of sunlight), sometimes energy demands are not met and so we turn back to non-renewable sources like fossil fuels. But if extra energy could be stored, it could be applied to compensate for days when less energy is produced. News of advancements being made by people who are really trying to find more environmentally-conscious options adds to a sense of motivation to keep working towards goals like these that really do make a difference. I wonder how far technology like this can be applied, from replacing a lot of fossil fuels with renewable energy to maybe even opening up other possibilities for other renewable sources.

Sources
Radford, T. (n.d.). Renewables burn a little brighter | Climate News Network.Climate News Network.